Interlayer Peeling in Multilayer Coating

When multiple layers are coated in sequence, insufficient adhesion between different layers causes interlayer peeling. When this defect appears in coating-formed products, it is usually closely related to the coating head precision, the rheological properties of the coating liquid, the substrate surface condition, or the curing process conditions. The distribution characteristics of coating defects (transverse/longitudinal/random) provide important clues for diagnosing coating head and curing system problems. Continuous occurrence will cause the functional performance of the coating to fall below standard, and coordinated troubleshooting is required from three aspects: coating liquid formulation, coating equipment, and curing process.

1. Comprehensive factor: insufficient wetting and bonding force between the primer layer and the topcoat layer. 2. Comprehensive factor: excessive curing of the primer layer leads to surface inertness. 3. Comprehensive factor: contamination at the interface between the two layers. 4. Substrate surface condition factor: The surface tension, cleanliness and microscopic roughness of the substrate are the basic conditions for coating adhesion and leveling. When the substrate surface tension is lower than the surface tension of the coating liquid, wetting is insufficient and craters occur; surface contamination leads to local adhesion failure, which is the primary direction for troubleshooting coating defects.

1. Process parameter optimization and adjustment: apply the topcoat after the primer layer is semi-cured (not fully cured) to ensure interlayer bonding by active groups. 2. Mold/tooling improvement and maintenance: set an intermediate anchor layer/adhesive layer between the primer and the topcoat. 3. Equipment inspection and system maintenance: ensure the primer surface is clean and dust-free before coating. 4. Systematic troubleshooting method: troubleshooting of coating problems follows the sequence of "substrate → coating liquid → coating head → curing → environment". First check the substrate surface tension (corona treatment effect) and cleanliness, then check the viscosity, solid content and degassing state of the coating liquid, next check the coating head gap and cleanliness, further verify the curing temperature and time, and finally evaluate the influence of ambient temperature, humidity and cleanliness. 5. Preventive management: establish standardized process parameter cards and quality control limits for each mold/product, and regularly conduct process capability index (CPK) evaluations. For recurring problems, use fishbone diagrams or the 5Why analysis method to trace the root cause, and solidify the countermeasures as PFMEA control points. Establish a regular equipment maintenance system, and implement life management for key tooling such as dies/spinnerets/calender rolls/coating heads.

This problem is a typical manifestation of interlayer peeling in multilayer coating in coating forming. The core of the solution lies in ensuring the substrate surface condition, optimizing the rheological properties of the coating liquid, and precisely controlling the curing process conditions. It is recommended to start from the two aspects of substrate and coating liquid, and gradually troubleshoot to the coating equipment and curing system.