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Material Analysis 15 visualizaciones

EVOH heat-sensitive degradation and discoloration

Fenómeno del problema
EVOH processing >230°C turns yellow-brown with decreased mechanics
Análisis de la causa
EVOH vinyl alcohol groups decompose by dealcoholization at high temperature, starting >230°C; excessive residence time aggravates decomposition
Solución
1) Strictly control the upper limit of processing temperature at 190-230°C; 2) Shorten high-temperature residence and increase rotation speed; 3) Add 0.1wt% heat stabilizer; 4) Select low vinyl alcohol content EVOH (ethylene 32-38%) with low decomposition tendency
Conclusión clave
EVOH heat-sensitive decomposition is caused by vinyl alcohol dealcoholization; temperature control is the fundamental countermeasure
EVOH thermal decomposition dealcoholization yellowing heat stabilizer temperature control

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