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Extrusion & Post 14 visualizaciones

MP blended with incompatible resin delamination

Fenómeno del problema
MP blended with polar resins such as PA/ABS, extrudate completely delaminated, mechanical properties extremely poor
Análisis de la causa
MP and polar resin have large polarity difference, compatibility is zero, interfacial adhesion extremely low, no compatibilizer used
Solución
1) use MP graft compatibilizer MP-g-MAH 2-5wt%; 2) add epoxy-type compatibilizer 1-2wt%; 3) MP addition <10wt% to keep the other resin as the continuous phase; 4) twin-screw high-shear compounding to disperse MP <0.3μm
Conclusión clave
blends with large polarity difference require a reactive compatibilizer to form chemical bonding at the interface to solve
MP blend delamination polarity difference MP-g-MAH reactive compatibilization interfacial bonding

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