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Extrusion & Post 13 visualizações

EMA Delamination When Blended with Incompatible Resins

Fenómeno do problema
When EMA is blended with polar resins such as PA/ABS, the extrudate completely delaminates, mechanical properties extremely poor
Análise das causas
The polarity difference between EMA and polar resins is large, compatibility is zero, interfacial adhesion extremely low, no compatibilizer used
Solução
1) Use EMA grafted compatibilizer EMA-g-MAH 2-5wt%; 2) Add 1-2wt% epoxy compatibilizer; 3) EMA addition <10wt% to keep the other resin as the continuous phase; 4) Twin-screw high-shear blending to disperse EMA <0.3μm
Conclusão principal
Blending with large polarity differences requires reactive compatibilizer to form chemical bonding at the interface to solve it
EMA blend delamination polarity difference EMA-g-MAH reactive compatibilization interfacial bonding

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